Reponse to Comment on: Corrected Debye–Hückel theory of electrolyte solutions

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

Modulation effects within the mean-field theory of electrolyte solutions.

The consequences of source charge and surface modulation are studied within the framework of the Poisson-Boltzmann theory of electrolyte solutions. Through a consideration of various examples, it is found that inherent modulation can lead to both like-charge attraction and overcharging effects.

OFFPRINT Surface tension of electrolyte solutions: A self-consistent theory

We study the surface tension of electrolyte solutions at the air/water and oil/water interfaces. Employing field-theoretical methods and considering short-range interactions of anions with the surface, we expand the Helmholtz free energy to first order in a loop expansion and calculate the excess surface tension. Our approach is self-consistent and yields an analytical prediction that reunites ...

Extension of the Dense System Equation of State to Electrolyte Solutions

In this work we have applied the Dense System Equation of State (DSEOS) to electrolyte solutions. We have found that this equation of state can predict the density of electrolyte solutions very accurately. It has been tested for different electrolytes solutions at different temperatures and compositions. A hypothetical binary model has been applied to find the dependencies of parameters of ...

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions